https://nova.newcastle.edu.au/vital/access/ /manager/Index en-au 5 Predicting plant uptake of cadmium: validated with long-term contaminated soils https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:29511 Cucumis sativa L. (cucumber). The parameter log Kf was predicted with soil pHca, logCEC and log OC. Transfer of soil pore-water Cd2+ to shoots was described with a power function (R2 = 0.73). The dataset was validated with 13 long-term contaminated soils (plus 2 control soils) ranging in Cd concentration from 0.2 to 300 mg kg−1. The series of equations predicting Cdshoot from pore-water Cd2+ were able to predict the measured data in the independent dataset (root mean square error = 2.2). The good relationship indicated that Cd uptake to cucumber shoots could be predicted with Cdpore and Cd2+ without other pore-water parameters such as pH or Ca2+. The approach may be adapted to a range of plant species.]]> Wed 23 Feb 2022 16:06:46 AEDT ]]> Bioaccessibility of barium from barite contaminated soils based on gastric phase in vitro data and plant uptake https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:24098 in vitro data for barite contaminated soils using the physiologically based extraction test (PBET) methodology. The existence of barite in plant tissue and the possibility of 'biomineralised' zones was also investigated using Scanning Electron Microscopy. Soils with low barium (Ba) concentrations showed a higher proportion of Ba extractability than barite rich samples. Barium uptake to spinach from soil was different between short term spiking studies and field weathered soils. Furthermore, Ba crystals were not evident in spinach tissue or acid digest solutions grown in barium nitrate spiked soils despite high accumulation. Barite was found in the plant digest solutions from barite contaminated soils only. Results indicate that under the conservative assumptions made, a child would need to consume extreme quantities of soil over an extended period to cause chronic health problems.]]> Wed 10 Nov 2021 15:05:34 AEDT ]]>